If you treat “parlous” as a morphological base (even though historically it’s a reduced form of perilous), you can systematically generate prefixal and suffixal derivatives. The distinction is important: most of these are formally valid in English word-formation, but only a subset are historically attested.

Prefix formations (negation, degree, relation):

• unparlous — logical negation (not dangerous), but essentially unattested

• non-parlous — later, more Latinate negation; not archaic in tone

• inparlous / imparlous — theoretically from Latin in-; not used in English here

• overparlous — excessively dangerous (constructed; not standard)

• underparlous — insufficiently dangerous (constructed; not idiomatic)

• outparlous — beyond dangerous (nonstandard)

• misparlous — prefix doesn’t semantically fit; effectively unusable

• disparlous — not viable; dis- doesn’t pair with this adjective

In practice, English never productively built prefixes onto “parlous.” Writers reverted to peril / perilous instead.

Suffix formations (more structurally natural):

• parlously — adverb (in a dangerous manner) — plausible and occasionally seen

• parlousness — noun (state of being dangerous) — rare but valid

• parlousity — theoretically possible, but not attested; -ity prefers Latinate bases like perilous → perilousness instead

• parlousful / parlousless — structurally possible, but linguistically awkward and unattested

• parloushood — not idiomatic; -hood attaches to nouns, not adjectives like this

• parlousdom — nonstandard formation

Key linguistic constraint

Because parlous is already a phonologically eroded descendant of “perilous,” English morphology “snaps back” to the root when forming families:

• peril → perilous → perilously → perilousness (fully productive)

• parlous remains lexically isolated, with only light extension (parlously, parlousness)

A writer in the register of John Milton would almost certainly avoid experimental forms like unparlous and instead shift constructions entirely: “secure,” “sure,” or “void of peril.”

So the complete answer is slightly paradoxical:
You can generate many forms mechanically, but historical English recognizes very few of them as legitimate.